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1.
《Mendeleev Communications》2022,32(5):629-631
The Michael–Mannich cascade cyclization of cyano olefins, ethyl 4,4,4-trifluoro-3-oxobutanoate, aromatic aldehydes and ammonium acetate provides convenient stereoselective formation of ethyl 5,5-dicyano-4,6-diaryl-2-hydroxy-2-(trifluoromethyl)piperidine-3-carboxylates with fourstereogenic centers and dialkyl 4,6-diaryl-5-cyano-2-hydroxy-2-(trifluoromethyl)piperidine-3,5-dicarboxylates with five stereogenic centers. Ammonium acetate plays dual role, acting as a base and as a nitrogen source. 相似文献
2.
András Gy. Németh Renáta Szabó Dr. Attila Domján Prof. György M. Keserű Dr. Péter Ábrányi-Balogh 《ChemistryOpen》2021,10(1):16-27
The development of a new three-component chromatography-free reaction of isocyanides, amines and elemental sulfur allowed us the straightforward synthesis of thioureas in water. Considering a large pool of organic and inorganic bases, we first optimized the preparation of aqueous polysulfide solution from elemental sulfur. Using polysulfide solution, we were able to omit the otherwise mandatory chromatography, and to isolate the crystalline products directly from the reaction mixture by a simple filtration, retaining the sulfur in the solution phase. A wide range of thioureas synthesized in this way confirmed the reasonable substrate and functional group tolerance of our protocol. 相似文献
3.
研究了V型三能级原子BEC与双模压缩光场相互作用系统中,忽略原子间相互作用和考虑原子间相互作用时光场的正交压缩和光子数压缩。结果表明,光场的正交压缩依赖于压缩参数,而光子数压缩与压缩参数、光场信号强度有关,在一定条件下,两种压缩可同时存在。原子间相互作用影响两种压缩的涨落随时间变化的周期,以及正交分量涨落随时间变化的幅度,而对光子数压缩涨落随时间变化的幅度几乎无影响。 相似文献
4.
Emmanuel DardennesÁrpád Kovács-Kulyassa Andrea RenzettiJanos Sapi Jean-Yves Laronze 《Tetrahedron letters》2003,44(2):221-223
Chiral pyrano- and pyrrolidino-fused tryptamines were prepared by a diasteroselective trimolecular condensation between indole, Garner's aldehyde and Meldrum's acid, followed by selective functional group transformations. 相似文献
5.
Panagiota G. Fragouli Hermis Iatrou Nikos Hadjichristidis 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):514-519
A series of five tetrablock quarterpolymers of styrene, isoprene, dimethylsiloxane, and 2-vinylpyridine with molecular weights varying from 117 × 103 to 177 × 103 and having different compositions were synthesized. The synthesis was based on recent advances in the controlled high-vacuum anionic polymerization of hexamethylcyclotrisiloxane and on the selective linking of poly(dimethylsiloxane)lithium with the chlorosilane group of the heterofunctional linking agent chloromethylphenylethylene dimethylchlorosilane. Combined characterization results by size exclusion chromatography, membrane osmometry, and NMR spectroscopy suggested that the synthesized multiblock multicomponent polymers had a high degree of structural and compositional homogeneity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 514–519, 2004 相似文献
6.
LUO You-Hua GE Zi-Ming 《理论物理通讯》2006,46(12)
In noncommutative space, we examine the problem of a noninteracting and harmonically trapped BoseEinstein condensate, and derive a simple analytic expression for the effect of spatial noncommutativity on energy spectrum of the condensate. It indicates that the ground-state energy incorporating the spatial noncommutativity is reduced to a lower level, which depends upon the noncommutativity parameter θ. The gap between the noncommutative space and commutative one for the ground-state level of the condensate should be a signal of spatial noncommutativity. 相似文献
7.
Subodh R Shenoy 《Pramana》2002,58(2):385-397
We obtain the dynamics in number and phase difference, for Bose condensates that tunnel between two wells of a double-well
atomic trap, using the (nonlinear) Gross-Pitaevskii equation. The dynamical equations are of the canonical form for the two
conjugate variables, and the Hamiltonian corresponds to that of a momentum-shortened pendulum, supporting a richer set of tunneling oscillation modes than for a superconductor Josephson junction, that has a
fixed-length pendulum as a mechanical model. Novel modes include ‘inverted pendulum’ oscillations with an average angle of
π; and oscillations about a self-maintained population imbalance that we term ‘macroscopic quantum self-trapping’. Other systems
with this phase-number nonlinear dynamics include two-component (interconverting) condensates in a single harmonic trap, and
He3B superfluids in two containers connected by micropores. 相似文献
8.
《Surface and interface analysis : SIA》2004,36(9):1304-1313
For rough heterogeneous samples, the contrast observed in XPS images may result from both changes in elemental or chemical composition and sample topography. Background image acquisition and subtraction are frequently utilized to minimize topographical effects so that images represent concentration variations in the sample. This procedure may significantly increase the data acquisition time. Multivariate statistical methods can assist in resolving topographical and chemical information from multispectral XPS images. Principal component analysis (PCA) is one method for identification of the highest correlation/variation between the images. Topography, which is common to all of the images, will be resolved in the first most significant component. The score of this component contains spatial information about the topography of the surface, whereas the loading is a quantitative representation of the topography contribution to each elemental/chemical image. The simple‐to‐use self‐modelling mixture analysis (Simplisma) method is a pure variable method that searches for the source of most differences in the data and therefore has the potential to distinguish between chemical and topographical phases in images. The mathematical background correction scheme is developed and validated by comparing results to the experimental background correction for samples with differing degrees of topography. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
9.
V. P. Maslov 《Theoretical and Mathematical Physics》2007,150(1):102-122
From the standpoint of thermodynamic averaging of fission microprocesses, we investigate the origin of radioactive release
in an NPP after an accident or after resource depletion. The genesis of the NPP release is interpreted as a new thermodynamic
phenomenon, a zeroth-order phase transition. This problem setting results in a problem in probabilistic number theory. We
prove the corresponding theorem leading to quantization of the Zipf law for the frequency of a zeroth-order phase transition
with different values of the jump of the Gibbs thermodynamic potential. We introduce the notion of hole dimension.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 150, No. 1, pp. 118–142, January, 2007. 相似文献
10.
We investigate a multicomponent anisotropic liquid system. The first spatial moment of the direct correlation function is taken into account to obtain asymptotic expressions for the pairwise correlation functions. In this approximation, we obtain the pairwise correlation functions that describe the system behavior not only in the critical-state neighborhood but also in the noncritical domain. We show that the critical parameters for the anisotropic system differ from those for the isotropic system. 相似文献